Chunlei Guo, the researcher who a year ago used intense laser light to
alter the properties of a variety of metals to render them pitch black,
has pushed the same process further in a paper in today's Applied
Physics Letters. He now believes it's possible to alter the properties
of any metal to turn it any color - even multi-colored iridescence
like a butterfly's wings.
Since the process changes the intrinsic surface properties of the metal
itself and is not just a coating, the color won't fade or peel, says
Guo, associate professor of optics at the Institute of Optics at the
University of Rochester. He suggests the possibilities are endless
- a cycle factory using a single laser to produce bicycles of
different colors; etching a full-color photograph of a family into the
refrigerator door; or proposing with a gold engagement ring that
matches your fiancée's blue eyes.
"Since the discovery of the black metal we've been determined to get
full control on getting metals to reflect only a certain color and
absorb the rest, and now we finally can make a metal reflect almost any
color we wish," says Guo. "When we first found the process that
produced a gold color, we couldn't believe it. We worked in the lab
until midnight trying to figure out what other colors we could make."
Guo and his assistant, Anatoliy Vorobeyv, use an incredibly brief but
incredibly intense laser burst that changes the surface of a metal,
forming nanoscale and microscale structures that selectively reflect a
certain color to give the appearance of a specific color or
combinations of colors.
The metal-coloring research follows up on Guo's breakthrough "black
metal" discovery in late 2006, when his research team was able to
create nanostructures on metal surfaces that absorbed virtually all
light, making something as simple as regular aluminum into one of the
darkest materials ever created.
Guo's black metal, with its very high absorption properties, is ideal
for any application where capturing light is desirable. The potential
applications range from making better solar energy collectors, to more
advanced stealth technology, he says. The ultra-brief/ultra-intense
light Guo uses is produced by a femtosecond laser, which produces
pulses lasting only a few quadrillionths of a second. A femtosecond is
to a second what a second is to about 32 million years. During its
brief burst, Guo's laser unleashes as much power as the entire electric
grid of North America does, all focused onto a spot the size of a
needlepoint.
The intense blast forces the surface of the metal to form
nanostructures - pits, globules, and strands that response
incoming light in different ways depending on the way the laser pulse
sculpted the structures. Since the structures are smaller than the
wavelength of light, the way they reflect light is highly dependent
upon their specific size and shape, says Guo. Varying the laser
intensity, pulse length, and number of pulses, allows Guo to control
the configuration of the nanostructures, and hence control what color
the metal reflects.
Guo and Vorobyev also achieve the iridescent coloring by creating
microscale lines covered with nanostructures. The lines, arranged in
regular rows, cause reflected light of different wavelengths to
interfere differently in different directions. The result is a piece of
metal that can appear solid purple from one direction, and gray from
another, or multiple colors all at once.
To alter an area of metal the size of a dime currently takes 30 minutes
or more, but the researchers are working on refining the technique.
Fortunately, despite the incredible intensity involved, the femtosecond
laser can be powered by a simple wall outlet, meaning that when the
process is refined, implementing it should be relatively simple.
The new process has worked on every metal Guo has tried, and the
results are so consistent that he believes it will work for every metal
known. His team is currently working to find the right tuning to create
the rest of the rainbow for the solid-colored metal, including red and
green.